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Methacrolein, 90%, stabilized, AcroSeal™, Thermo Scientific Chemicals

CAS: 78-85-3 Molecular Formula: C4H6O Molecular Weight (g/mol): 70.09 MDL Number: MFCD00006974 InChI Key: STNJBCKSHOAVAJ-UHFFFAOYSA-N Synonym: methacrolein,methacrylaldehyde,2-propenal, 2-methyl,isobutenal,2-methylacrolein,2-methylpropenal,2-methyl-2-propenal,methylacrylaldehyde,2-methylenepropanal,methacrylic aldehyde PubChem CID: 6562 IUPAC Name: 2-methylprop-2-enal SMILES: CC(=C)C=O

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Alpha beta-unsaturated carbonyl compounds

PubChem CID	6562
CAS	78-85-3
Molecular Weight (g/mol)	70.09
MDL Number	MFCD00006974
SMILES	CC(=C)C=O
Synonym	methacrolein,methacrylaldehyde,2-propenal, 2-methyl,isobutenal,2-methylacrolein,2-methylpropenal,2-methyl-2-propenal,methylacrylaldehyde,2-methylenepropanal,methacrylic aldehyde
IUPAC Name	2-methylprop-2-enal
InChI Key	STNJBCKSHOAVAJ-UHFFFAOYSA-N
Molecular Formula	C4H6O

Sodium triethylborohydride, 1M solution in THF, AcroSeal™, Thermo Scientific Chemicals

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Organo-Metalloid Compounds

Linear Formula	NaB(C₂H₅)₃H
Molecular Weight (g/mol)	121.99
Color	Colorless
Physical Form	Solution
Chemical Name or Material	Sodium triethylborohydride
SMILES	[Na+].CC[BH-](CC)CC
InChI Key	YDTZLEUIYNMRLQ-UHFFFAOYSA-N
Density	0.8900g/mL
PubChem CID	23667700
Name Note	1M solution in THF
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture
MDL Number	MFCD00011704
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. May cause respiratory irritation. In contact with water releases flammable gas. Highly flammable liquid and vapor. May form explosive peroxides. Reacts violentl
Solubility Information	Solubility in water: rzacts.
Packaging	AcroSeal™ Glass bottle
Flash Point	−17°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	sodium triethylborohydride,sodium triethylborate,sodium triethylhydroborate,sodium triethylhydridoborate,sodium triethylhydroborate 1-,sodium triethylborohydride solution,sodium triethyl-? 2-boranuide,sodiumtriethylborohydride 1m in toluene
IUPAC Name	sodium;triethylboron(1-)
Molecular Formula	C6H16BNa
EINECS Number	241-903-1
Formula Weight	121.99
Specific Gravity	0.89

Diisobutylaluminium hydride, 1.0M solution in heptane, AcroSeal™, Thermo Scientific Chemicals

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General Chemistry Solutions

Linear Formula	[(CH₃)₂CHCH₂]₂AIH
Color	Undesignated
Physical Form	Solution
Chemical Name or Material	Diisobutylaluminium hydride
Merck Index	15, 3212
Concentration	19.5 to 20.5% (DIBAL-H, on Al basis)
Density	0.7000g/mL
Name Note	1.0M Solution in Heptane
Fieser	01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS	142-82-5
Health Hazard 3	GHS P Statement: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Avoid breathing dust/fume/gas/mist/vapors/spray. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Do NOT induce vomiting. Avoid release to the environment. Store in a dry place. Store in a closed container. WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.
MDL Number	MFCD00008928
Health Hazard 2	GHS H Statement: Causes severe skin burns and eye damage. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Very toxic to aquatic life with long lasting effects. In contact with water releases flammable gases which may ignite spontaneously.
Flash Point	−1°C
Solubility Information	Solubility in water: vigorous reaction. Other solubilities: miscible with saturated aliphatic and aromatic, hydrocarbons
Health Hazard 1	Danger
Synonym	DIBAL-H, 1.0M solution in heptane
Beilstein	04, IV, 4400
Molecular Formula	C₈H₁₉Al
Formula Weight	142.22
Specific Gravity	0.7
Melting Point	-70.0°C

Ethylmagnesium bromide, ca. 3.2M solution in 2-MeTHF; AcroSeal™, Thermo Scientific Chemicals

CAS: 925-90-6 Molecular Formula: C2H5BrMg Molecular Weight (g/mol): 133.27 MDL Number: MFCD00000043 InChI Key: TWTWFMUQSOFTRN-UHFFFAOYSA-M Synonym: ethylmagnesium bromide,grignard reagent,ethyl magnesium bromide,ethylmagnesiumbromide,ethylmagnesiumbromide,ethylmagnesium bromide solution, 1.0 m in thf,ethylmagnesium bromide solution, 1.0 m in thf,ethylmagnesium bromide solution, 3.0 m in diethyl ether,ethylmagnesiumbromid,ethylmagnesiumbromid,ethylmagnesium bromid PubChem CID: 101914 IUPAC Name: bromo(ethyl)magnesium SMILES: CC[Mg]Br

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General Chemistry Solutions

PubChem CID	101914
CAS	925-90-6
Molecular Weight (g/mol)	133.27
MDL Number	MFCD00000043
SMILES	CC[Mg]Br
Synonym	ethylmagnesium bromide,grignard reagent,ethyl magnesium bromide,ethylmagnesiumbromide,ethylmagnesiumbromide,ethylmagnesium bromide solution, 1.0 m in thf,ethylmagnesium bromide solution, 1.0 m in thf,ethylmagnesium bromide solution, 3.0 m in diethyl ether,ethylmagnesiumbromid,ethylmagnesiumbromid,ethylmagnesium bromid
IUPAC Name	bromo(ethyl)magnesium
InChI Key	TWTWFMUQSOFTRN-UHFFFAOYSA-M
Molecular Formula	C2H5BrMg

Borane-methyl sulfide complex, 2M solution in THF, AcroSeal™, Thermo Scientific Chemicals

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General Chemistry Solutions

Linear Formula	(CH₃)₂S·BH₃
Molecular Weight (g/mol)	75.96
InChI Key	RMHDLBZYPISZOI-UHFFFAOYSA-N
Density	0.8500g/mL
PubChem CID	9833925
Name Note	2M Solution in Tetrahydrofuran
Fieser	04,191; 05,47; 06,64; 08,49; 10,49; 14,52; 17,50
RTECS Number	PV5080000
Formula Weight	75.95
Color	Colorless to Yellow
Physical Form	Solution
Chemical Name or Material	Borane-methyl sulfide complex
SMILES	B.CSC
Merck Index	15, 1336
Concentration	1.80 to 2.20M
CAS	75-18-3
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
MDL Number	MFCD00013189
Health Hazard 2	GHS H Statement May cause respiratory irritation. Causes skin irritation. Causes serious eye damage. Harmful if swallowed. In contact with water releases flammable gases which may ignite spontaneously. Highly flammable liquid and vapor. May form explosive peroxides. Reacts violently with water. Suspected of causing cancer. May cause drowsiness or dizziness.
Flash Point	−17°C
Solubility Information	Solubility in water: reacts. Other solubilities: soluble in ethyl ether, tetrahydrofurane, hexane,, toluene, methylene chloride and other aprotic, solvents
Health Hazard 1	Danger
Synonym	dimethyl sulfide borane,borane-methyl sulfide complex,borane dimethyl sulfide complex,borane-dimethyl sulfide,dimethyl sulfideborane,dimethyl sulfide trihydroboron,borane-dimethyl sulfide complex,borane methylsulfide,borane dimethylsulfide,borane dms
TSCA	TSCA
IUPAC Name	(methylsulfanyl)methane borane
Molecular Formula	C2H9BS
EINECS Number	236-313-6
Specific Gravity	0.85

Borane dimethyl sulfide complex, 2M solution in toluene, AcroSeal™, Thermo Scientific Chemicals

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Metalloid Salts

Linear Formula	(CH₃)₂S·BH₃
Molecular Weight (g/mol)	75.96
Chemical Name or Material	Borane dimethyl sulfide complex
SMILES	B.CSC
Merck Index	15,1336
InChI Key	RMHDLBZYPISZOI-UHFFFAOYSA-N
Density	0.8560g/mL
PubChem CID	9833925
CAS	108-88-3
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture
MDL Number	MFCD00013189
Health Hazard 2	GHS H Statement Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. May cause drowsiness or dizziness. May cause respiratory irritation. Causes skin irritation
Packaging	AcroSeal™ Glass bottle
Flash Point	7°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	dimethyl sulfide borane,borane-methyl sulfide complex,borane dimethyl sulfide complex,borane-dimethyl sulfide,dimethyl sulfideborane,dimethyl sulfide trihydroboron,borane-dimethyl sulfide complex,borane methylsulfide,borane dimethylsulfide,borane dms
Molecular Formula	C2H9BS
EINECS Number	236-313-6
Formula Weight	75.95
Specific Gravity	0.856

Iron(0) pentacarbonyl, AcroSeal™, Thermo Scientific Chemicals

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Transition Metal Salts

Isobutylmagnesium chloride, 2M solution in diethyl ether, AcroSeal™, Thermo Scientific Chemicals

CAS: 60-29-7 Molecular Weight (g/mol): 116.87 MDL Number: MFCD00000471 ChEBI: CHEBI:75272

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Dihydrocoumarins

CAS	60-29-7
Molecular Weight (g/mol)	116.87
ChEBI	CHEBI:75272
MDL Number	MFCD00000471

Ethylmagnesium bromide, 0.9M solution in THF, AcroSeal™, Thermo Scientific Chemicals

CAS: 925-90-6 Molecular Formula: C2H5BrMg Molecular Weight (g/mol): 133.27 MDL Number: MFCD00000043 InChI Key: TWTWFMUQSOFTRN-UHFFFAOYSA-M Synonym: ethylmagnesium bromide,grignard reagent,ethyl magnesium bromide,magnesium, bromoethyl,bromoethylmagnesium,bromoethylmagnesium,ethylmagnesium bromide solution, 3.0 m in diethyl ether,ethylmagnesium bromide solution, 3.0 m in diethyl ether,ethylmagnesiumbromid,ethylmagnesium bromid,ethylmagnesium bromid PubChem CID: 101914 SMILES: CC[Mg]Br

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General Chemistry Solutions

PubChem CID	101914
CAS	925-90-6
Molecular Weight (g/mol)	133.27
MDL Number	MFCD00000043
SMILES	CC[Mg]Br
Synonym	ethylmagnesium bromide,grignard reagent,ethyl magnesium bromide,magnesium, bromoethyl,bromoethylmagnesium,bromoethylmagnesium,ethylmagnesium bromide solution, 3.0 m in diethyl ether,ethylmagnesium bromide solution, 3.0 m in diethyl ether,ethylmagnesiumbromid,ethylmagnesium bromid,ethylmagnesium bromid
InChI Key	TWTWFMUQSOFTRN-UHFFFAOYSA-M
Molecular Formula	C2H5BrMg

2-Mesitylmagnesium bromide, 1M solution in THF, AcroSeal™, Thermo Scientific Chemicals

CAS: 2633-66-1 Molecular Formula: C9H11BrMg Molecular Weight (g/mol): 223.40 MDL Number: MFCD00009663 InChI Key: VZMGGVXGYWKQPB-UHFFFAOYSA-M Synonym: 2-mesitylmagnesium bromide,grignard reagent,mesitylmagnesium bromide,2-mesitylmagnesium bromide solution,2-mesitylmagnesium bromide solution,yxvsitsudrgill-uhfffaoysa-m,yxvsitsudrgill-uhfffaoysa-m,magnesium,bromo 2,4,6-trimethylphenyl,2,4,6-trimethylphenylmagnesium bromide, 1m in 2-methf,2,4,6-trimethylphenylmagnesium bromide, 1m in 2-methf,2-mesitylmagnesium bromide solution, 1.0 m in diethyl ether PubChem CID: 5098599 IUPAC Name: bromo(3,4,5-trimethylphenyl)magnesium SMILES: CC1=CC([Mg]Br)=CC(C)=C1C

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Alkaline Earth Metal Salts

PubChem CID	5098599
CAS	2633-66-1
Molecular Weight (g/mol)	223.40
MDL Number	MFCD00009663
SMILES	CC1=CC([Mg]Br)=CC(C)=C1C
Synonym	2-mesitylmagnesium bromide,grignard reagent,mesitylmagnesium bromide,2-mesitylmagnesium bromide solution,2-mesitylmagnesium bromide solution,yxvsitsudrgill-uhfffaoysa-m,yxvsitsudrgill-uhfffaoysa-m,magnesium,bromo 2,4,6-trimethylphenyl,2,4,6-trimethylphenylmagnesium bromide, 1m in 2-methf,2,4,6-trimethylphenylmagnesium bromide, 1m in 2-methf,2-mesitylmagnesium bromide solution, 1.0 m in diethyl ether
IUPAC Name	bromo(3,4,5-trimethylphenyl)magnesium
InChI Key	VZMGGVXGYWKQPB-UHFFFAOYSA-M
Molecular Formula	C9H11BrMg

Ethylmagnesium bromide, 3M in diethyl ether, AcroSeal™, Thermo Scientific Chemicals

CAS: 925-90-6 Molecular Formula: C2H5BrMg Molecular Weight (g/mol): 133.27 MDL Number: MFCD00000043 InChI Key: TWTWFMUQSOFTRN-UHFFFAOYSA-M Synonym: ethylmagnesium bromide,grignard reagent,ethyl magnesium bromide,ethylmagnesiumbromide,ethylmagnesiumbromide,bromoethylmagnesium,ethylmagnesium bromide solution, 3.0 m in diethyl ether,etmgbr,etmgbr,ethylmagnesiumbromid,ethylmagnesium bromid PubChem CID: 101914 IUPAC Name: magnesium;ethane;bromide SMILES: CC[Mg]Br

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Organic metal halides

PubChem CID	101914
CAS	925-90-6
Molecular Weight (g/mol)	133.27
MDL Number	MFCD00000043
SMILES	CC[Mg]Br
Synonym	ethylmagnesium bromide,grignard reagent,ethyl magnesium bromide,ethylmagnesiumbromide,ethylmagnesiumbromide,bromoethylmagnesium,ethylmagnesium bromide solution, 3.0 m in diethyl ether,etmgbr,etmgbr,ethylmagnesiumbromid,ethylmagnesium bromid
IUPAC Name	magnesium;ethane;bromide
InChI Key	TWTWFMUQSOFTRN-UHFFFAOYSA-M
Molecular Formula	C2H5BrMg

Lithium bis(trimethylsilyl)amide, 1M solution in THF/Ethylbenzene, AcroSeal™, Thermo Scientific Chemicals

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Organo-Metalloid Compounds

Molecular Weight (g/mol)	167.33
Color	Yellow to Brown
Physical Form	Turbid Solution
Chemical Name or Material	Lithium bis(trimethylsilyl)amide
SMILES	[Li+].C[Si](C)(C)[N-][Si](C)(C)C
InChI Key	YNESATAKKCNGOF-UHFFFAOYSA-N
Density	0.8900g/mL
PubChem CID	2733832
Name Note	1M Solution in THF/Ethylbenzene
Percent Purity	18 to 22% active base (as LiNSi)
Fieser	04,296; 05,393; 07,197; 12,280; 13,165; 14,194
CAS	100-41-4
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF ON SKIN (or ha
MDL Number	MFCD00008261
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. May cause respiratory irritation. Highly flammable liquid and vapor. Suspected of causing cancer. Reacts violently with water. May form explosive peroxides.<br/
Solubility Information	Solubility in water: decomposes
Flash Point	−21°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	lithium bis trimethylsilyl amide,lithium hexamethyldisilazide,lihmds,lhmds,hexamethyldisilazane lithium salt,unii-rc4n1i108m,lithiumbis trimethylsilyl amide,lithium bis trimethylsilyl azanide,lithium hexamethyldisilazane,lithium bis-trimethylsilyl amide
TSCA	TSCA
IUPAC Name	lithium;bis(trimethylsilyl)azanide
Molecular Formula	C₆H₁₈LiNSi₂
EINECS Number	223-725-6
Formula Weight	167.33
Specific Gravity	0.89

Dimethoxydimethylsilane, 95+%, AcroSeal™, Thermo Scientific Chemicals

CAS: 1112-39-6 Molecular Formula: C4H12O2Si Molecular Weight (g/mol): 120.22 MDL Number: MFCD00025691 InChI Key: JJQZDUKDJDQPMQ-UHFFFAOYSA-N Synonym: dimethyldimethoxysilane,silane, dimethoxydimethyl,kbm 22,unii-a3qdb1rs1c,dimethyl dimethoxysilane,dimethoxy dimethyl silane,a3qdb1rs1c,dimethoxy-dimethylsilane,dimethyl dimethoxy silane,dimethyl dimethoxy silicane PubChem CID: 66187 IUPAC Name: dimethoxydimethylsilane SMILES: CO[Si](C)(C)OC

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Organo-Metalloid Compounds

PubChem CID	66187
CAS	1112-39-6
Molecular Weight (g/mol)	120.22
MDL Number	MFCD00025691
SMILES	CO[Si](C)(C)OC
Synonym	dimethyldimethoxysilane,silane, dimethoxydimethyl,kbm 22,unii-a3qdb1rs1c,dimethyl dimethoxysilane,dimethoxy dimethyl silane,a3qdb1rs1c,dimethoxy-dimethylsilane,dimethyl dimethoxy silane,dimethyl dimethoxy silicane
IUPAC Name	dimethoxydimethylsilane
InChI Key	JJQZDUKDJDQPMQ-UHFFFAOYSA-N
Molecular Formula	C4H12O2Si

Ethylmagnesium chloride, 2.7M (25 wt.%) solution in THF, AcroSeal™, Thermo Scientific Chemicals

CAS: 2386-64-3 Molecular Formula: C2H5ClMg Molecular Weight (g/mol): 88.82 MDL Number: MFCD00000472 InChI Key: ZWNJJACKPNTXHY-UHFFFAOYSA-M Synonym: ethylmagnesium chloride,chloroethylmagnesium,ethylmagnesiumchloride,magnesium, chloroethyl,etmgcl,chloro ethyl magnesium,ethyl magnesium chloride,chloroethyl-magnesiu,ethyl magnesiumchloride,ethylmagnesium chloride solution PubChem CID: 75432 IUPAC Name: magnesium;ethane;chloride SMILES: CC[Mg]Cl

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Organic metal halides

PubChem CID	75432
CAS	2386-64-3
Molecular Weight (g/mol)	88.82
MDL Number	MFCD00000472
SMILES	CC[Mg]Cl
Synonym	ethylmagnesium chloride,chloroethylmagnesium,ethylmagnesiumchloride,magnesium, chloroethyl,etmgcl,chloro ethyl magnesium,ethyl magnesium chloride,chloroethyl-magnesiu,ethyl magnesiumchloride,ethylmagnesium chloride solution
IUPAC Name	magnesium;ethane;chloride
InChI Key	ZWNJJACKPNTXHY-UHFFFAOYSA-M
Molecular Formula	C2H5ClMg

Methylmagnesium chloride, 3M (22 wt.%) solution in THF, AcroSeal™, Thermo Scientific Chemicals

CAS: 676-58-4 Molecular Formula: CH3ClMg Molecular Weight (g/mol): 74.79 MDL Number: MFCD00000468 InChI Key: RQNMYNYHBQQZSP-UHFFFAOYSA-M Synonym: methylmagnesium chloride,chloromethylmagnesium,chloro methyl magnesium,magnesium, chloromethyl,memgcl,methylmagnesiumchloride,methyl magnesium chloride,unii-m5e1132g4w,ch3mgcl,qmabhcaih@ PubChem CID: 12670 IUPAC Name: chloro(methyl)magnesium SMILES: C[Mg]Cl

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General Chemistry Solutions

PubChem CID	12670
CAS	676-58-4
Molecular Weight (g/mol)	74.79
MDL Number	MFCD00000468
SMILES	C[Mg]Cl
Synonym	methylmagnesium chloride,chloromethylmagnesium,chloro methyl magnesium,magnesium, chloromethyl,memgcl,methylmagnesiumchloride,methyl magnesium chloride,unii-m5e1132g4w,ch3mgcl,qmabhcaih@
IUPAC Name	chloro(methyl)magnesium
InChI Key	RQNMYNYHBQQZSP-UHFFFAOYSA-M
Molecular Formula	CH3ClMg

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