Phenylmagnesium bromide, 3M in 2-MeTHF, Thermo Scientific Chemicals

Description

 

Phenyl magnesium bromide is the suitable reagent used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It may be used for synthesis of  1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol, (3-(2-Dithiobenzoatepropionyl)propyl)dimethylmethoxysilane, reversible addition-fragmentation chain transfer polymerization (RAFT)-silane agent, series of o-substituted benzophenones.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Phenyl magnesium bromide is the suitable reagent used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It may be used for synthesis of  1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, 6-benzyl-1,

Specifications

Chemical Identifiers

• CAS: 100-58-3
• Molecular Formula: C6H5BrMg
• Molecular Weight (g/mol): 181.32
• MDL Number: MFCD00000038
• InChI Key: ANRQGKOBLBYXFM-UHFFFAOYSA-M
• Synonym: phenylmagnesium bromide, bromophenylmagnesium, magnesium, bromophenyl, phmgbr, phenylmagnesiumbromide, bromo phenyl magnesium, phenyl magnesium bromide, phenylmagnesium bromide solution, 3.0 m in diethyl ether, bromomagnesiobenzene, phenyhnagnesium bromide, grignard reagent
• PubChem CID: 66852
• IUPAC Name: magnesium;benzene;bromide
• SMILES: Br[Mg]C1=CC=CC=C1

• Linear Formula: C₆H₅MgBr
• Quantity: 100 mL
• UN Number: UN2924
• Sensitivity: Air and moisture sensitive
• Solubility Information: Reacts with water.
• Formula Weight: 181.31
• Concentration or Composition (by Analyte or Components): 3M in 2-MeTHF
• Chemical Name or Material: Phenylmagnesium bromide

Safety and Handling

Hazard Category	H225-H302-H314-H335
Hazard Statement	GHS H Statement H225-H314 Highly flammable liquid and vapor. Causes severe skin burns and eye damage.
Precautionary Statement	P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.
TSCA	Yes
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only