Diisopropyl azodicarboxylate, 94%, Thermo Scientific Chemicals

Description

Diisopropyl azodicarboxylate is used as an important reagent in the production of many organic compounds. It is used in association with triphenyl phosphine in Mitsunobu reaction of alcohols, acids and amides. It acts as reactant in the preparation of chromenes resembling classical cannabinoids, norbornene-based guanidine-rich polymers and acceptor-donor-acceptor organic dyes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diisopropyl azodicarboxylate is used as an important reagent in the production of many organic compounds. It is used in association with triphenyl phosphine in Mitsunobu reaction of alcohols, acids and amides. It acts as reactant in the preparation of chromenes resembling classical cannabinoids, norbornene-based guanidine-rich polymers and acceptor-donor-acceptor organic dyes.

Solubility
Immiscible with water.

Notes
Store in cool place. Light sensitive. Incompatible with strong oxidizing agents, strong bases, alcohols and metallic salts. Decomposes violently at or above: 100 ⁰C.

Specifications

Chemical Identifiers

• CAS: 2446-83-5
• Molecular Formula: C8H14N2O4
• Molecular Weight (g/mol): 202.21
• MDL Number: MFCD00008875
• InChI Key: VVWRJUBEIPHGQF-KTKRTIGZSA-N
• Synonym: z-n-propan-2-yloxy carbonyl imino propan-2-yloxy formamide
• PubChem CID: 56776520
• IUPAC Name: propan-2-yl (NZ)-N-propan-2-yloxycarbonyliminocarbamate
• SMILES: CC(C)OC(=O)N=NC(=O)OC(C)C

• Melting Point: 3°C to 5°C
• Density: 1.027
• Boiling Point: 74°C to 75°C (0.3 mmHg)
• Flash Point: 160°C (320°F)
• Odor: Pungent
• Refractive Index: 1.42
• Quantity: 100 g
• UN Number: UN3082
• Beilstein: 1912326
• Sensitivity: Light sensitive
• Solubility Information: Immiscible with water.
• Formula Weight: 202.21
• Percent Purity: 94%
• Chemical Name or Material: Diisopropyl azodicarboxylate

Safety and Handling

Hazard Category	H315-H319-H335-H373
Hazard Statement	GHS H Statement H315-H319-H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P260-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P314-P332+P313-P362-P501c
DOTInformation	Transport Hazard Class: 9; Packing Group: III; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
EINECSNumber	219-502-8
TSCA	No
Recommended Storage	Keep cold

SDS

RUO – Research Use Only