Bromoacetaldehyde dimethyl acetal, 97+%, stab. with potassium carbonate, Thermo Scientific Chemicals

Description

2-Bromo-1,1-dimethoxyethane (Bromoacetaldehyde dimethyl acetal) was used in the synthesis of 2,3-O-acetal via reaction with 2,3-diol in the presence of 10-camphorsulphonic acid (CSA). 2-bromo-1,1-dimethoxyethane was used to react with 4-hydroxylbenzaldehyde, and finally aldehyde substituted prodrug was generated by TFA-mediated deacetalization.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Bromo-1,1-dimethoxyethane (Bromoacetaldehyde dimethyl acetal) was used in the synthesis of 2,3-O-acetal via reaction with 2,3-diol in the presence of 10-camphorsulphonic acid (CSA). 2-bromo-1,1-dimethoxyethane was used to react with 4-hydroxylbenzaldehyde, and finally aldehyde substituted prodrug was generated by TFA-mediated deacetalization.

Solubility
Insoluble in water.

Notes
Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture.

Specifications

Chemical Identifiers

• CAS: 7252-83-7
• Molecular Formula: C4H9BrO2
• Molecular Weight (g/mol): 169.018
• MDL Number: MFCD00000213
• InChI Key: FUSFWUFSEJXMRQ-UHFFFAOYSA-N
• Synonym: bromoacetaldehyde dimethyl acetal, ethane, 2-bromo-1,1-dimethoxy, 2,2-dimethoxyethyl bromide, dimethylbromoacetal, 1-bromo-2,2-dimethoxyethane, 2,2-dimethoxybromoethane, 2-bromoacetaldehyde dimethyl acetal, bromoacetoaldehyde dimethyl acetal, bromoacetaldehyde dimethylacetal, acetaldehyde, bromo-, dimethyl acetal
• PubChem CID: 81672
• IUPAC Name: 2-bromo-1,1-dimethoxyethane
• SMILES: COC(CBr)OC

• Density: 1.435
• Boiling Point: 150°C
• Flash Point: 54°C (129°F)
• Refractive Index: 1.445
• Linear Formula: BrCH₂CH(OCH₃)₂
• Quantity: 250 g
• UN Number: UN2929
• Beilstein: 1280132
• Sensitivity: Moisture sensitive
• Solubility Information: Insoluble in water.
• Formula Weight: 169.03
• Percent Purity: ≥97%
• Chemical Name or Material: Bromoacetaldehyde dimethyl acetal, Stabilized with potassium carbonate

Safety and Handling

Hazard Category	H226-H301-H315-H319-H330-H335
Hazard Statement	GHS H Statement H301-H330-H226-H315-H319-H335 Toxic if swallowed. Fatal if inhaled. Flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P284-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 6.1; Packing Group: II; Proper Shipping Name: TOXIC LIQUIDS, FLAMMABLE, ORGANIC, N.O.S.
EINECSNumber	230-669-6
TSCA	Yes
Recommended Storage	Keep cold

SDS

RUO – Research Use Only