3-(Ethoxycarbonyl)propylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles, Thermo Scientific Chemicals

Description

 

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Palladium-catalyzed coupling with [4-(methoxycarbonyl)benzyllzinc bromide then selective hydrolysis of the tert-butyl ester trifluoroacetic acid, in design and synthesis of pyridone-containing inhibitors.

Solubility

Specifications

Chemical Identifiers

• CAS: 131379-39-0
• Molecular Formula: C6H11BrO2Zn
• Molecular Weight (g/mol): 260.436
• MDL Number: MFCD00671977
• InChI Key: XPARCVGSTPKNNR-UHFFFAOYSA-M
• Synonym: zinc 2+ ion 4-ethoxy-4-oxobutan-1-ide bromide
• PubChem CID: 4390801
• IUPAC Name: bromozinc(1+);ethyl butanoate
• SMILES: CCOC(=O)CC[CH2-].[Zn+]Br

• Density: 0.976
• Linear Formula: CH₃CH₂O₂C(CH₂)₃ZnBr
• Quantity: 50 mL
• UN Number: UN3399
• Sensitivity: Air sensitive
• Solubility Information: Reacts with water.
• Formula Weight: 260.44
• Chemical Name or Material: 3-(Ethoxycarbonyl)propylzinc bromide, Packaged under Argon in resealable ChemSeal™ bottles

Safety and Handling

Hazard Category	H225-H260-H302-H314-H335-H336-H351
Hazard Statement	GHS H Statement H225-H261-H314-H351-H335 Highly flammable liquid and vapor. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation.
Precautionary Statement	P201-P202-P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA	No
Recommended Storage	Keep cold; Store under Argon

SDS

RUO – Research Use Only