3-Bromo-4-methylaniline, 97%, Thermo Scientific Chemicals

Description

3-Bromo-4-methylaniline is used in the synthesis of 1,7-dihalo Tröger?s base isomers. It is suitable for use to investigate the reactions of distonic 4-(N,N,N-trimethylammonium)-2-methylphenyl and 5-(N,N,N-trimethylammonium)-2-methylphenyl radical cations with O2 by ion-trap mass spectrometry.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3-Bromo-4-methylaniline is used in the synthesis of 1,7-dihalo Tröger′s base isomers. It is suitable for use to investigate the reactions of distonic 4-(N,N,N-trimethylammonium)-2-methylphenyl and 5-(N,N,N-trimethylammonium)-2-methylphenyl radical cations with O2 by ion-trap mass spectrometry.

Solubility
Insoluble in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 7745-91-7
• Molecular Formula: C7H8BrN
• Molecular Weight (g/mol): 186.05
• MDL Number: MFCD00134176
• InChI Key: GRXMMIBZRMKADT-UHFFFAOYSA-N
• Synonym: 3-bromo-p-toluidine, p-toluidine, 3-bromo, benzenamine, 3-bromo-4-methyl, 3-bromo-4-methyl-phenylamine, 3-bromo-1,4-toluidine, 4-amino-2-bromotoluene, 3-bromo-4-methylbenzenamine, 3-bromo-4-methylphenylamine, 3-bromo-para-toluidine, 3-bromo-4-methyl-aniline
• PubChem CID: 82187
• IUPAC Name: 3-bromo-4-methylaniline
• SMILES: CC1=CC=C(N)C=C1Br

• Melting Point: 25°C to 28°C
• Boiling Point: 254°C to 257°C
• Flash Point: >110°C (230°F)
• Odor: Characteristic
• Refractive Index: 1.6115
• Quantity: 25 g
• UN Number: UN2811
• Beilstein: 1562057
• Solubility Information: Insoluble in water.
• Formula Weight: 186.06
• Percent Purity: 97%
• Chemical Name or Material: 3-Bromo-4-methylaniline

Safety and Handling

Hazard Category	H301-H315-H319-H335
Hazard Statement	GHS H Statement H301-H311-H315-H319 Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation.
Precautionary Statement	P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
DOTInformation	Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
EINECSNumber	231-807-8
RTECSNumber	XU4375000
TSCA	No
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only