1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate, Thermo Scientific Chemicals

Description

Hydrogenation

1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for isomerization of allylic ethers of glycerol and glucose to the corresponding 1-propenyl ethers. It is also used as a catalyst in hydrogenation reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 38465-86-0
• Molecular Formula: C34H38F6IrP3
• Molecular Weight (g/mol): 845.81
• MDL Number: MFCD00064800
• InChI Key: LXKHQEQLBSJJCO-JXNOXZOESA-N
• Synonym: 1,5-cyclooctadiene bis methyldiphenylphosphine iridium i hexafluorophosphate, 1,5-cyclooctadiene bis methyldiphenylphosphine ir, 1,5-cyclooctadienebis methyldiphenylphosphine iridium i hexafluorophosphate, 1z,5z-cycloocta-1,5-diene; iridium; methyl diphenyl phosphane; hexafluorophosphate, iridium 1+ 1,5-cyclooctadiene, z,z-bis methyldiphenylphosphane hexafluorophosphate
• PubChem CID: 5702663
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;iridium;methyl(diphenyl)phosphane;hexafluorophosphate
• SMILES: [Ir+].F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.CP(C1=CC=CC=C1)C1=CC=CC=C1.CP(C1=CC=CC=C1)C1=CC=CC=C1

• Melting Point: 224°C (decomposition)
• Quantity: 2 g
• Sensitivity: Air and moisture sensitive
• Solubility Information: Soluble in acetone; Insoluble in water.
• Formula Weight: 845.79
• Physical Form: Crystalline
• Chemical Name or Material: 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate

Safety and Handling

Hazard Category	H302+H312+H332-H315-H319-H335
Hazard Statement	GHS H Statement H301-H315-H319-H335 Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
TSCA	No
Recommended Storage	Ambient temperatures; Store under Argon

SDS

RUO – Research Use Only